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Abstract Young exoplanets are attractive targets for atmospheric characterization to explore the early phase of planetary evolution and the surrounding environment. Recent observations of the 10 Myr young Neptune-sized exoplanet K2-33b revealed that the planet’s transit depth drastically decreases from the optical to near-infrared wavelengths. Thao et al. suggested that a thick planetary haze and/or stellar spots may be the cause; however, even the best-fit model only barely explains the data. Here, we propose that the peculiar transmission spectrum may indicate that K2-33b possesses a circumplanetary dust ring; an analog of Jupiter’s dust ring. We demonstrate that the ring could produce a steep slope in the transmission spectrum even if its optical depth is as low as ∼10 −2 . We then apply a novel joint atmosphere-ring retrieval to K2-33b and find that the ring scenario could well explain the observed spectrum for various possible ring compositions. Importantly, the dust ring also exhibits prominent ring particle absorption features of ring particles around ∼10 μ m, whose shape and strength depend on the composition of the ring. Thus, future observations by JWST-MIRI would be able to test not only the ring hypothesis but also, if it indeed exists, to constrain the composition of the ring—providing a unique opportunity to explore the origins of the dust ring around its parent planet, soon after the planetary system’s formation. 

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.